It just a little bit more tricky.
What you are looking for is hidden in the 2 rightmost bits of the HKEY_LOCAL_MACHINE\SYSTEM\CurrentControlSet\Control\Print\Printer\Your_Printer\Attributes
The codes are
0 - use spooler and start print immediately
1 - use spooler and start after last page is spooled
2 - print directly to printer.
Don't change other bits.
And the trick is that after the change you have to restart "Printer Spooler" service to activate the new settings .
Good luck.