This is not a supported configuration, and the fact that 3 users are working without any problems is amazing. (BTW, even having the PST file on a server isn't a supported configuration - cf
http://support.microsoft.com/kb/297019/en-us)
For my customers who want to do something like this, I recommend MAPILAB Groupware Server -
http://www.mapilab.com/groupware/server/?ga