Well,
Then there is no simple way to merge your drives. Either you can install Win XP Pro .
Partially solutions are folder redirection. You can redirect some of system folders to drive D.
Folders related to user profile can be redirected using TweakUI utility.
Also you can redirect Program Files folder, however there are some warnings from Microsoft about doing so.
Also you can move your pagefile to D: , it will also increase free space.